Water Analysis in the Petroleum Industry

Corrosion:pressure as water rises to the surface. Scale is
The causes of corrosion vary but are almost alwaysalmost always calcium carbonate, however, calcium
related to water chemistry.sulfate, strontium sulfate, and barium sulfate can
- pH - acidic or basic solutions are corrosiveform in waters high in sulfate.
- TDS - high salt content results in higher ionicLaboratory Analysis:
strength and leads to corrosionDetermining the chemical composition of production
- Chloride - forms soluble iron chloridewater can give operators an indication of the
- Sulfate - food for bacteria that form corrosivetendency of the water to generate scale or cause
hydrogen sulfidecorrosion. Proper treatment of the water based on
- Bacteria - can produce organic acids that lower pHthe chemical analysis prevents scale or corrosion and
Corrosion Products:minimizes downtime increasing production.
A corrosion Product is a solid that appears as scaleWater analyzes can be plotted as Stiff diagrams
(clogs pipes) and is a result of corrosion somewherecreating a unique image of each water layer within a
in the system. Typical Corrosion Products are:well. Future analyzes can be plotted and compared to
- Iron carbonatethe original Stiff diagram. Significant changes in major
- Iron sulfideions could indicate leaks or scale formation.
- Iron oxideSudden increases in iron and manganese imply that
- Trace metals such as Mn, Cr, Cu, Ni, and Mo canthere is corrosion down hole.
indicate the source of the corrosion.These are just a few of the possibilities of an often
Scale:overlooked valuable resource. Production engineers
Scale is caused by a decrease in the saturation limitsearching for increased production of oil and gas
of ions in the formation water. Water at depthproducing wells should consider the routine monitoring
generally holds more salt in solution than water at theof water from their wells.
surface. Scale can form in pipes due to a loss in